… (L) Variation in the Redox Systems [L2Ru (μ??boptz) RuL2] n, boptz= 3, 6??bis (2??oxidophenyl)??1, 2, 4, 5??tetrazine, and L= acetylacetonate, 2, 2′??bipyridine, or 2?? …

…, R Jimenez??Aparicio, W Kaim, GK Lahiri

Index: Patra, Srikanta; Sarkar, Biprajit; Maji, Somnath; Fiedler, Jan; Urbanos, Francisco A.; Jimenez-Aparicio, Reyes; Kaim, Wolfgang; Lahiri, Goutam Kumar Chemistry - A European Journal, 2006 , vol. 12, # 2 p. 489 - 498

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Citation Number: 2

Abstract

Abstract The new compounds [(acac) 2 Ru (μ-boptz) Ru (acac) 2](1),[(bpy) 2 Ru (μ-boptz) Ru (bpy) 2](ClO 4) 2 (2-(ClO 4) 2), and [(pap) 2 Ru (μ-boptz) Ru (pap) 2](ClO 4) 2 (3-(ClO 4) 2) were obtained from 3, 6-bis (2-hydroxyphenyl)-1, 2, 4, 5-tetrazine (H 2 boptz), the crystal structure analysis of which is reported. Compound 1 contains two antiferromagnetically coupled (J=− 36.7 cm− 1) Ru III centers. We have investigated the role of both the donor ...