Synthesis of 4, 6-dideoxyfuranoses through the regioselective and diastereoselective oxyfunctionalization of a dimethylphenylsilyl-substituted chiral homoallylic …

W Adam, CR Saha-Möller…

Index: Adam, Waldemar; Prechtl, Frank; Richter, Markus J.; Smerz, Alexander K. Tetrahedron Letters, 1995 , vol. 36, # 28 p. 4991 - 4994

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Citation Number: 26

Abstract

The 4, 6-dideoxyfuranoses 10a and 10b have been synthesized by starting from the readily available E-5-dimethylphenylsilyl-2-hexene-4-ol (1) and employing successively three versatile oxyfunctionalization methods, namely photooxygenation, metal-catalyzed