The Synthesis of 8-Hydroxy-1-keto-4-methyl-1, 2, 3, 5, 6, 7-hexahydronaphthalene1

MS Newman, AB Mekler

Index: Newman,M.S.; Mekler,A.B. Journal of the American Chemical Society, 1960 , vol. 82, p. 4039 - 4041

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Citation Number: 15

Abstract

BY hfELVIN s. NEWMAN AND ARLEN B. bfEKLER2 RECEIVED JANUARY 27, 1960 ... The conversion of 1,6-diketo-8a-methyl-1,2,3,4,~,7,8,8a-octahydronaphthalene (I) to 8-hydroxy-l-keto -4-methyl-l,2,3, 5,6,7-hexahydronaphthalene (111) by means of sodium methoxide in methanol is described; I11 forms a stable copper chelate with ease. ... In connection with another problem, we wish ed to prepare a quantity of methyl r-(6-rnethyl-3-keto- 1-cyclohexen-1-y1 ...