Chemiluminogenic features of 10-methyl-9-(phenoxycarbonyl) acridinium trifluoromethanesulfonates alkyl substituted at the benzene ring in aqueous media

…, AD Roshal, A Wróblewska, B Zadykowicz…

Index: Krzyminski, Karol; Ozog, Agnieszka; Malecha, Piotr; Roshal, Alexander D.; Wroblewska, Agnieszka; Zadykowicz, Beata; Blazejowski, Jerzy Journal of Organic Chemistry, 2011 , vol. 76, # 4 p. 1072 - 1085

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Citation Number: 28

Abstract

10-Methyl-9-(phenoxycarbonyl) acridinium trifluoromethanesulfonates bearing alkyl substituents at the benzene ring were synthesized, purified, and identified. In the reaction with OOH− in basic aqueous media, the cations of the compounds investigated were converted to electronically excited 10-methyl-9-acridinone, whose relaxation was accompanied by chemiluminescence (CL). The kinetic constants of CL decay, relative ...