… of nickel triad metals. 3. He (I) and He (II) spectra of trans-[(PEt3) 2MXY](M= Pd, Pt; X= Y= C. tplbond. CH, C. tplbond. CMe, C. tplbond. N; X= Cl, Y= C. tplbond. N) and …

JN Louwen, R Hengelmolen, DM Grove…

Index: Louwen, Jaap N.; Hengelmolen, Rudy; Grove, David M.; Oskam, Ad; DeKock, Roger L. Organometallics, 1984 , vol. 3, p. 908 - 918

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Citation Number: 26

Abstract

Ultraviolet photoelectron (UP) spectra of the title compounds and Hartree-Fock-Slater (HFS) MO calculations for the model compounds trans-[(PHB) zMXY](M= Pd, X= Y= WH, C= C- CH3, C k N and X= C1, Y= C= N; M= Pt (relativistic effects included), X= Y= C 4-H and X= C1, Y= C= N) are reported. The upper valence bands in the spectra can be assigned in good agreement with the HFS calculations. Among the features demonstrated is a strong A ...