Oxidation of Electron-Deficient Sulfides to Sulfones Using HOF. cntdot. CH3CN

R Beckerbauer, BE Smart, Y Bareket…

Index: Beckerbauer, Richard; Smart, Bruce E.; Bareket, Yifat; Rozen, Shlomo Journal of Organic Chemistry, 1995 , vol. 60, # 19 p. 6186 - 6187

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Citation Number: 20

Abstract

The direct oxidation of sulfides to sulfones is a wellknown, easy process for many alkyl and aryl substrates, but complications can arise with less reactive, electrondeficient sulfides, particularly perfluoroalkylated ones. Only a few methods for converting perfluoroalkyl sulfides to sulfones have been reported, and they typically require reagents like chromic anhydride or concentrated H2Od trifluoroacetic acidtrifluoroacetic anhydride, l although ...