1??Phenyl??1, 2??cyclohexadiene: Generation, Interception by Activated Olefins, Dimerisation and Trimerisation

…, D Moigno, H Fischer, S Deuerlein…

Index: Christl, Manfred; Schreck, Michael; Fischer, Thomas; Rudolph, Marcus; Moigno, Damien; Fischer, Hartmut; Deuerlein, Stephan; Stalke, Dietmar Chemistry - A European Journal, 2009 , vol. 15, # 42 p. 11256 - 11265

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Citation Number: 6

Abstract

Abstract Four possible precursors of 1-phenyl-1, 2-cyclohexadiene (2) were examined, namely, 6, 6-dibromo-1-phenylbicyclo [3.1. 0] hexane,(1α, 5α, 6α)-6-bromo-6-fluoro-1- phenylbicyclo [3.1. 0] hexane, 1-bromo-2-phenylcyclohexene and 1-bromo-6- phenylcyclohexene. All four compounds could be converted into 2, as demonstrated by the products of the interception of 2 with activated olefins. Styrene, 1, 1-diphenylethene, ...