Thermal decomposition of 2??amino??3??aziridino??1, 4??naphthoquinones

…, F Claudi, G Cristalli, M Grifantini…

Index: Antonini, Ippolito; Claudi, Francesco; Cristalli, Gloria; Grifantini, Mario; Martelli, Sante Journal of Heterocyclic Chemistry, 1981 , vol. 18, p. 399 - 404

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Abstract

Abstract The course of the thermal decomposition of various 2-amino-3-substituted aziridino- 1, 4-naphthoquinones (Ia-g) was investigated. In all the cases, the thermal decomposition gave variable amounts of 2, 3-diamino-1, 4-naphthoquinone (II) and of substituted 1, 2, 3, 4, 5, 10-hexahydrobenzo [g] quinoxaline-5, 10-diones (IIIa-g) with complete stereospecificity. The decomposition of the aziridines Ib, f also gave significative amounts of 2-amino-3- ...