Darzens Reaction of Acyl Phosphonates with α-Bromo Ketones: Selective Synthesis of cis-and trans-Epoxyphosphonates

AS Demir, M Emrullahoglu, E Pirkin…

Index: Zhang, Guolin; Li, Zheng; Wang, Xicun Synthetic Communications, 2002 , vol. 32, # 20 p. 3107 - 3112

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Citation Number: 15

Abstract

... Volume: Page: ... and, therefore, has been recognized as one of the most significant C−C, C−O bond-forming processes in synthetic organic chemistry ... together with side products 5 and 6 (Table 1, entry 6). The diastereomeric ratio was found to be 35/20 (trans/cis ...