Synthetic Communications

Trimethylsilylazide/KN3/18-Crown-6. Formation and Curtius Rearrangement of Acyl Azides from Unreactive Acid Chlorides

JD Warren, JB Press

Index: Synthetic Communications, , vol. 10, # 2 p. 107 - 110

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Citation Number: 13

Abstract

Page 1. SYNTHETIC COMMUNICATIONS, 10(2), 107-110 (1980) ... these acyl azides in situ has yielded isocyanates via the Curtius rearrangement. 1 ,2 However, we have noted that the acyl chlorides I and I1 did not react with TMSA, even under forcing conditions (eg ten-fold ...