Oxidative alkylamination of azinones is a promising method for the preparation of a great variety of alkylaminoazinones. Treatment of 6, 8-dimethyl-2-R-pyrimido [4, 5-c] pyridazin-3, 5, 7 (2H, 6H, 8H)-triones 7, 1, 3-dimethyl-5-R-pteridin-2, 4, 6 (1H, 3H, 6H)-triones 8 and 1, 3, 6-trimethylpyrimido [4, 5-d] pyrimidin-2, 4, 7 (1H, 3H, 6H)-trione 9 with alkylamine/ AgPy2MnO4 or alkylamine/KMnO4 has been shown to produce their 4-, 7-and 5- ...