Tetrahedron

Studien in der caranreihe—II: Über die pyrolyse der acetate von (+)(1r: 4r: 6s)-caran-trans-4-ol und (+)(1r: 4s: 6s)-caran-cis-4-ol;(+)(1r: 6s)-Δ4-caren und (+)(1R: 4R)- …

K Gollnick, G Schade

Index: Gollnick,K.; Schade,G. Tetrahedron, 1966 , vol. 22, p. 123 - 132

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Citation Number: 17

Abstract

Pyrolysis of the acetate of (+)(1R: 4R: 6S)-Carane-trans-4-ol (I) 10 Torr and temperatures between 386 and 604° yields acetic acid and a mixture of the hydrocarbons (+)(1R: 6S)-Δ4- Carene (III),(+)(1R: 6S)-Δ3-Carene (IV), and (+)(1R: 4R)-trans-Δ2, 8-p-menthadiene (VI), the composition of which depends on the temperature. The same hydrocarbons are formed by pyrolysis of (+)(1R: 4S: 6S)-carane-cis-4-ol (II).