Hydrogen bonds in phenylboronic acids with polyoxaalkyl substituents at ortho-position

…, A Dąbrowska, B Gierczyk, P Klimentowska…

Index: Adamczyk-Wozniak, Agnieszka; Cyranski, Michal K.; Dabrowska, Aldona; Gierczyk, Blazej; Klimentowska, Paulina; Schroeder, Grzegorz; Zubrowska, Anna; Sporzynski, Andrzej Journal of Molecular Structure, 2009 , vol. 920, # 1-3 p. 430 - 435

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Citation Number: 12

Abstract

Phenylboronic acids with polyoxaalkyl substituents at ortho position were synthesized from the corresponding bromides. Structures in solid state, determined by single crystal X-ray diffraction, reveal the presence of inter-and intramolecular hydrogen bonds. Presence of several oxygen atoms in oxaalkyl chains enables the formation of intramolecular hydrogen bonds by B (OH) 2 group with different oxygen centers which lead to the formation of ...