Journal of fluorine chemistry

Thermolytic transformations of polyfluoroorganic compounds XXIX. Formation of fluorine-containing styrenes by reactions of benzotrichloride and related compounds …

KV Dvornikova, VE Platonov, GG Yakobson

Index: Dvornikova,K.V.; Platonov,V.E. Journal of Fluorine Chemistry, 1985 , vol. 28, p. 99

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Citation Number: 13

Abstract

Abstract Reactions of polyfluorobenzotrichlorides, benzotrichloride and α, α- dichloroperfluoroethylbenzene with sources of difluorocarbene and other dihalocarbenes lead to the formation of polyfluorostyrenes. Formation of polyfluorostyrenes is shown to proceed possibly by initial dihalocarbene insertion into the C Cl bond of the benzylic position with subsequent dechlorination of the resulting product.