Synthesis and luminescence of poly (phenylacetylene) s with pendant iridium complexes and carbazole groups

…, G Zhou, HJ Bolink, J Arias??Pardilla

Index: Vicente, Jose; Gil-Rubio, Juan; Zhou, Guijiang; Bolink, Henk J.; Arias-Pardilla, Joaquin Journal of Polymer Science, Part A: Polymer Chemistry, 2010 , vol. 48, # 17 p. 3744 - 3757

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Citation Number: 20

Abstract

Abstract Poly (phenylacetylene) s containing pendant phosphorescent iridium complexes have been synthesized and their electrochemical, photo-and electroluminescent properties studied. The polymers have been synthesized by rhodium-catalyzed copolymerization of 9- (4-ethynylphenyl) carbazole (CzPA) and phenylacetylenes (C∧ N) 2 Ir (κ 2-O, O′-MeC (O) CHC (O) C 6 H 4 C [TRIPLE BOND] CH-4)(C∧ N= κ 2-N, C 1-2-(pyridin-2-yl) phenyl (Ir ...