Preparation of-(3S)-2, 3-dimethylpentanal by reaction of (+)-tris [(2S)-1, 2-dimethylbutoxy] methane (I) with carbon monoxide and hydrogen

R Rossi, P Pino, F Piacenti, L Lardicci…

Index: Rossi,R. et al. Journal of Organic Chemistry, 1967 , vol. 32, p. 842 - 844

Full Text: HTML

Citation Number: 3

Abstract

On the basis of these data and of the distribution of isomeric products obtained by hydroformylation of the two intermediate olefins, the amounts of I1 and IV derived from reactions A+ D and C+ E may be evaluated. Thus of a total of 39.5% 11,. 0.33% is due to reaction D and 1.62% to reaction E. Analogous considerations may be made for IV. By subtracting the amounts of II. owing to reactions D and E calculated in this way (from total ...