Oxyfunctionalization of Non-Natural Targets by Dioxiranes. 5. Selective Oxidation of Hydrocarbons Bearing Cyclopropyl Moieties1

L D'Accolti, A Dinoi, C Fusco, A Russo…

Index: Leriverend,P.; Conia,J.-M. Bulletin de la Societe Chimique de France, 1966 , p. 121 - 125

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Citation Number: 20

Abstract

... 1 In 2, the rich-in-p character cyclopropane ring orbitals are constrained by the rigid framework to lay in the favorable “bisected” orientation 1 with respect to the p component of the “α” methylene C−H bonds; the latter p orbitals interact with the dioxirane empty σ* O - O orbital ...