Journal of the American Chemical Society

α-(2, 4, 5, 7-Tetranitro-9-fluorenylideneaminoöxy)-propionic Acid, a New Reagent for Resolution by Complex Formation1

MS Newman, WB Lutz

Index: Newman; Lutz Journal of the American Chemical Society, 1956 , vol. 78, p. 2469,2470

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Citation Number: 48

Abstract

The preparation of (+)-and (-)-cu-(2, 4, 5, 7-tetranitro-9-fluorenylideneaminoox~ j-propionic acid (111) by reaction of (-)-and (+)-or-(isopropylideneamino6xy)-propionic acid (I) with 2, 4, 5, 7-tetranitro-9-fluorenone(11) is described as well as the use of (+)-and (-)-I11 for partial resolution of 1-naphthyl 2-butyl ether and methyl CY-(1-anthry1)-propionate. Several complexes of I1 with polycyclic aromatic hydrocarbons are described. The melting points ...