Polycyanurate Networks with Enhanced Segmental Flexibility and Outstanding Thermochemical Stability

…, JT Reams, TJ Groshens, LC Baldwin, LM Lubin…

Index: Guenthner, Andrew J.; Davis, Matthew C.; Ford, Michael D.; Reams, Josiah T.; Groshens, Thomas J.; Baldwin, Lawrence C.; Lubin, Lisa M.; Mabry, Joseph M. Macromolecules, 2012 , vol. 45, # 24 p. 9707 - 9718

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Citation Number: 13

Abstract

The synthesis and physical properties of cyanurate networks formed from two new tricyanate monomers, 1, 3, 5-tris [(4-cyanatophenylmethyl] benzene and 3, 5-bis [(4- cyanatophenylmethyl)] phenylcyanate, are reported and compared to those of 1, 1, 1-tris [(4- cyanatophenyl)] ethane (also known as ESR-255). All three networks possessed somewhat different aromatic contents and cross-link densities; however, the thermochemical stability ...