Methylamine-deuterium isotope exchange equilibriums in the gaseous and liquid phases

JH Rolston, J Den Hartog, JP Butler…

Index: Rolston, J. H.; Hartog, J. den; Butler, J. P. Journal of Physical Chemistry, 1980 , vol. 84, # 17 p. 2170 - 2179

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Citation Number: 2

Abstract

The deuterium-protium separation factor, a, between molecular hydrogen and liquid methylamine in the presence of potassium methylamide catalyst has been measured at low deuterium concentrations over the temperature range-50 to+ 5 “C. The separation factor is about 10% larger than that for liquid ammonia, and its dependence upon absolute temperature, T, is given by In a= 0.1135+(240.05/T)+(43989/p). The equilibrium constant, ...