Catalytic conversions of chloroolefins over iron oxide nanoparticles 2. Isomerization of dichlorobutenes over iron oxide nanoparticles stabilized on the surface of …

TN Rostovshchikova, MS Korobov, DA Pankratov…

Index: Rostovshchikova; Korobov; Pankratov; Yurkov; Gubin Russian Chemical Bulletin, 2005 , vol. 54, # 6 p. 1425 - 1432

Full Text: HTML

Citation Number: 3

Abstract

Abstract Nanosized iron oxides stabilized on the surface of ultradispersed poly (tetrafluoroethylene)(UPTFE) granules were synthesized by the thermal destruction of iron formate in boiling bed of UPTFE on the surface of heated mineral oil. The particle size of nanoparticles (∼ 6 nm) containing 5, 10, and 16 wt.% Fe depends weakly on the temperature of synthesis and iron to polymer ratio. The metal state is determined by the ...