Asymmetric [3+ 2] Cycloadditions of Allenoates and Dual Activated Olefins Catalyzed by Simple Bifunctional N??Acyl Aminophosphines

H Xiao, Z Chai, CW Zheng, YQ Yang…

Index: Xiao, Hua; Chai, Zhuo; Zheng, Chang-Wu; Yang, Ying-Quan; Liu, Wen; Zhang, Jun-Kang; Zhao, Gang Angewandte Chemie - International Edition, 2010 , vol. 49, # 26 p. 4467 - 4470

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Citation Number: 174

Abstract

Recently, phosphine-catalyzed [3+ 2] cycloadditions of allenoates with electron-deficient olefins and imines—a process which provides efficient access to a variety of synthetically useful carbo-and heterocycles from readily available starting materials—have received considerable research interest [1, 2] since the pioneering works of Lu and co-workers.[1j] As a result of continuing efforts from many research groups in this field, an array of new ...