The Journal of Organic Chemistry

Activation of dithiocarbamate by 2-halothiazolium salts

H Sugimoto, I Makino, K Hirai

Index: Sugimoto, Hirohiko; Makino, Itsuo; Hirai, Kentaro Journal of Organic Chemistry, 1988 , vol. 53, # 10 p. 2263 - 2267

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Citation Number: 35

Abstract

Activation of dithiocarbamate salts with 2-halo-3-alkyl-4-phenylthiazolium salt and subsequent one-pot nu-cleophilic reaction with N, s, and 0 nucleophiles provided substituted thioureas, dithiocarbamates, and thiocarbamates or amides, respectively, under very mild conditions. A useful thiocarbonyl-transfer reaction is also described that consists of activation of imidazolodithiocarbamate and a subsequent one-pot nucleophilic reaction.( ...