Organometallics

Intramolecular Aminoalkene Hydroamination Catalyzed by Magnesium Complexes Containing Multidentate Phenoxyamine Ligands

X Zhang, TJ Emge, KC Hultzsch

Index: Zhang, Xiaoming; Emge, Thomas J.; Hultzsch, Kai C. Organometallics, 2010 , vol. 29, # 22 p. 5871 - 5877

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Citation Number: 53

Abstract

The magnesium complexes L2Mg i Pr (L2= 4-tert-butyl-6-(triphenylsilyl)-2-[bis ((3- (dimethylamino) propyl) amino) methyl] phenoxyl) and L3Mg i Pr (L3= 4-tert-butyl-6- (triphenylsilyl)-2-[benzyl ((3-(dimethylamino) propyl) amino) methyl] phenoxyl) supported by potentially tetradentate and tridentate triphenylsilyl-substituted phenoxyamine ligands have been prepared and fully characterized. The complexes were shown to be competent ...