Chromatographic method for the determination of conditional equilibrium constants for the carbamate formation reaction from amino acids and peptides in aqueous …

JG Chen, M Sandberg, SG Weber

Index: Chen, Jian-Ge; Sandberg, Mats; Weber, Stephen G. Journal of the American Chemical Society, 1993 , vol. 115, # 16 p. 7343 - 7350

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Citation Number: 13

Abstract

Abstract: A novel and sensitive method has been developed and evaluated for the study of carbamate formation equilibria of amino acids and peptides in aqueous solution. The method is based on reversed-phase liquid chromatography with cetyltrimethylammonium bromide. The reliability of the method was established by comparing the results determined from the present study with the few data in the literature. The relaxation rate of the ...