Palladium-catalyzed cross coupling of 1, 4-butanesultam and 1, 3-propanesultam with a variety of aryl halides was found to provide the desired products in 62–93% isolated yield using Xantphos as ligand. The Pd-catalyzed reaction was found to be superior to the analogous Cu-catalyzed reaction based on product yields, reaction rates, and substrate scope.