Synthesis and characterization of new tetra-substituted porphyrins with exo-donor carboxylic groups as building blocks for supramolecular architectures: Catalytic and …

…, F Ragaini, E Gallo, M Ranocchiari…

Index: Carlucci, Lucia; Ciani, Gianfranco; Maggini, Simona; Proserpio, Davide M.; Ragaini, Fabio; Gallo, Emma; Ranocchiari, Marco; Caselli, Alessandro Journal of Porphyrins and Phthalocyanines, 2010 , vol. 14, # 9 p. 804 - 814

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Citation Number: 5

Abstract

The synthesis of the novel 5, 10, 15, 20-tetrakis (4-carboxy-2, 6-dimethylbiphenyl) porphyrin (H2TCDMBP) and an improvement in the synthesis of 5, 10, 15, 20-tetrakis (4- carboxybiphenyl) porphyrin (H2TCBP) is reported. The presence of long diphenyl units on meso-positions of both porphyrins are in accord with their use as building blocks for the synthesis of porous MOFs. The porphyrins reactivity towards metal cations has been ...