Phthalocyanines and related compounds: XLV. Nucleophilic substitution of chlorine in tetrachlorophthalonitrile: Synthesis of aryloxy-aubstituted phthalonitriles and …

…, VM Negrimovskii, EA Luk'yanets

Index: Volkov; Avramenko; Negrimovskii; Luk'yanets Russian Journal of General Chemistry, 2007 , vol. 77, # 6 p. 1126 - 1133

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Citation Number: 14

Abstract

Abstract Nucleophilic substitution of chlorine in tetrachlorophthalonitrile by the reaction with aryloxy anions is studied. Depending on the reactant ratio, the products of substitution of one, two, and/or three chlorine atoms are formed. Their tetramerization gives aryloxychloro- substituted phthalocyanines having the absorption band in the near-IR range.