The Journal of Physical Chemistry

Electron spin resonance, electron spin echo modulation, and electron nuclear double resonance studies of the photoionization of N-alkyl-N, N', N'-trimethylbenzidine …

C Stenland, L Kevan

Index: Stenland, Chris; Kevan, Larry Journal of Physical Chemistry, 1993 , vol. 97, # 19 p. 5177 - 5184

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Citation Number: 7

Abstract

N-Alkyl-N, N', N'-trimethylbenzidines (C, TMB, n= 1-6, 8) were synthesized and photoionized in rapidly frozen anionic and cationic micelIes. The photoyields of the cation radicals were investigated by electron spin resonance spectroscopy. Electron spin echo modulation spectroscopy and proton matrix electron nuclear double resonance were used to determine the relative location of the photoproduced cation radical with respect to the deuterated ...