The Journal of Organic Chemistry

Reactivity of phosphacarbamates: transfer of the carbamate group promoted by metal-assisted electrophilic attack at the carbon dioxide moiety

M Aresta, E Quaranta

Index: Aresta, Michele; Quaranta, Eugenio Journal of Organic Chemistry, 1988 , vol. 53, # 17 p. 4153 - 4154

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Citation Number: 48

Abstract

(3) We observed a temperature effect; for example, Jda( ... J,,@,,S, of 2b were 3.4 and 9.2 Hz at 44 OC, 3.1 and 9.5 Hz at $3 OC, 2.8 an'd 10.0 Hz at -3 OC, 2.4 and 10.4 Hz at -13 “C, and 1.5 and 10.5 Hz at -35 oc. (4) For a review, see: Lemieux, R. U. Chem. SOC. Rev. 1978, 7, 423. Lemieux, RU Frontiers of Chemistry; Laidler, K. J.; Ed.; Pergamon: New York, 1982; p 1 and references cited therein. ... Yuan Wang, Peter G. Goekjian David M. Ryckman, ...