Conversion of terpenic compounds to ω-ketonitriles

AV Tkaohev, AV Rukavishnikov…

Index: Tkachev, A.V.; Rukavishnikov, A.V.; Chibirjaev, A.M.; Volodarsky, L.B. Synthetic Communications, 1990 , vol. 20, # 14 p. 2123 - 2132

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Citation Number: 17

Abstract

AV Tkaohev* , AVRukaviahnikov, AMChibirjaev, LBVolodarsky ... Novosibtrsk Institute of Organic Chemistry Novoeibirsk. 630090. USSR ... ABSTRACT: ConverBion of unsaturated terpenoids with trisubstituted oarbon-oarbon double bond into a-amino oximes followed by treatment with phosphorw pentaohlo- ride results in the formation of seco-terpenio o-keto nitrlles. ... Copyright 'fl I ')YO by Wdrrrl Dekker, Inr ... The reactions allow one to transform unsaturated