Russian Journal of Organic Chemistry

Reaction of 2, 2-dinitromalononitrile with arylalkenes

IG Pak, AG Tyrkov

Index: Pak; Tyrkov Russian Journal of Organic Chemistry, 2011 , vol. 47, # 9 p. 1284 - 1286

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Abstract

Abstract 2, 2-Dinitromalononitrile reacted with phenylethene and 1-phenylpropene through intermediate aci-nitromalononitrile ester and subsequent 1, 3-dipolar cycloaddition of the second alkene molecule with formation of substituted 5-phenyltetrahydroisoxazole-3, 3- dicarbonitriles. Reactions of 2, 2-dinitromalononitrile with 2-phenylpropene or p- methoxyphenylethene resulted in the formation of 2-(1-aryl-2-nitroethyl)-2- ...

~45%

~48%

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