Carbonyl-Stabilized Sulfonium Ylids. Reaction with Schiff Bases

AJ Speziale, CC Tung, KW Ratts…

Index: Speziale,A.J. et al. Journal of the American Chemical Society, 1965 , vol. 87, p. 3460 - 3462

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Citation Number: 49

Abstract

Discussion The stabilization of carbanions by the inductive and pd overlap effects of an adjacent phosphorus atom has provided a class of P-ylids which have been shown to provide one of the most useful carbon-carbon bond forming reactions.'In the same manner as phosphorus, sulfur may also expand its valence shell utilizing 3d orbitals to stabilize an adjacent carbanion. The synthetic utility of S-ylids has not been as fully explored as the P- ...