Construction of co-ordination networks of 1, 6-bis (4′-pyridyl)-2, 5-diazahexane with silver (I) and copper (I). Structural diversity through change in metal ions and …

BL Fei, WY Sun, KB Yu, WX Tang

Index: Fei, Bao-Li; Sun, Wei-Yin; Yu, Kai-Bei; Tang, Wen-Xia Journal of the Chemical Society, Dalton Transactions, 2000 , # 5 p. 805 - 811

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Citation Number: 56

Abstract

A novel flexible tetradentate ligand 1, 6-bis (4′-pyridyl)-2, 5-diazahexane (BPDH) was synthesized, and its coordination networks with silver (I) and copper (I) salts chracterized by X-ray single-crystal structure analysis and electrospray mass spectrometry (ES-MS). The network topologies are found to depend greatly on the counter anions and metal ions employed during the reaction and crystallization. The structure of [Ag (BPDH)] NO31 is a ...