Vinylborane formation in rhodium-catalyzed hydroboration of vinylarenes. Mechanism versus borane structure and relationship to silation

JM Brown, GC Lloyd-Jones

Index: Journal of the American Chemical Society, , vol. 116, # 3 p. 866 - 878

Full Text: HTML

Citation Number: 99

Abstract

... 1992, 114, 8863-9. 0 1994 American Chemical Society ... SOC., Vol. ... tentative suggestion to explain part of the pathway would be that oxidation produces a phosphine-poor complex which encourages the formation of vinylborane in a similar manner to the chemistry described for ...

Total syntheses of ningalin A, lamellarin O, lukianol A, and...

[Hori, Mikio; Ozeki, Hiroyuki; Iwamura, Tatsunori; Shimizu, Hiroshi; Kataoka, Tadashi; Iwata, Noriyuki Heterocycles, 1990 , vol. 31, # 1 p. 23 - 26]

An Improved Bouveault− Blanc Ester Reduction with Stabilized...

[Bodnar, Brian S.; Vogt, Paul F. Journal of Organic Chemistry, 2009 , vol. 74, # 6 p. 2598 - 2600]

Dod-S-Me and methyl 6-morpholinohexyl sulfide (MMS) as new o...

[Patra, Pranab K.; Nishide, Kiyoharu; Fuji, Kaoru; Node, Manabu Synthesis, 2004 , # 7 p. 1003 - 1006]

A Practical Olefin Hydroboration under Liquid-Liquid Phase T...

[Synlett, , # 7 p. 997 - 998]

Regio-and enantiocontrol in the room-temperature hydroborati...

[Journal of the American Chemical Society, , vol. 126, # 30 p. 9200 - 9201]