Inorganic Chemistry

Reactions of platinum (II) aqua complexes. 3. Multinuclear (nitrogen-15, platinum-195, carbon-13, and proton) NMR study of reactions of aqua and hydroxo complexes …

TG Appleton, JR Hall, SF Ralph

Index: Appleton, Trevor G.; Hall, John R.; Ralph, Stephen F. Inorganic Chemistry, 1985 , vol. 24, p. 673 - 677

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Citation Number: 2

Abstract

Pt (HzO) 42+ with glycine (glyH) gives Pt (HzO) 3 (glyH-0) 2+ and Pt (H20) 2 (glyH-0) 2+ and with (methy1imino) diacetic acid (midaHz) Pt (H20) 3 (midaH2-0) 2+. The mida complex, when heated, does not give mer-Pt (mida)(HzO) but a complex mixture of species, probably with Pt-NCH2COz-Pt bridging. cis-Pt (NH3) 2 (H20) 2+ with glycine gives~ is-Pt (NH~)~(glyH- O)(H~ 0)~+, characterized by lsN, 19&, 13C, and IH NMR, which only slowly converts to ...