The Journal of Organic Chemistry

Bridged ring compounds. VIII. 1-Halobicyclo [2.2.-2] octanes

Z Suzuki, K Morita

Index: Suzuki,Z.; Morita,K. Journal of Organic Chemistry, 1967 , vol. 32, p. 31 - 34

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Citation Number: 16

Abstract

Convenient syntheses of 1-chloro-, 1-bromo-, and l-iodobicyclo [2.2. 2] octanes are described. Reaction of l-methoxybicyclo [2.2. 2] octanes with acetyl halides in the presence of stannic chloride afforded l-halobicyclo-[2.2. 2] octanes in moderate yields. An analogous reaction of 4-methoxybicyclo [2.2. 2] octan-2-ones with acetyl chloride afforded a mixture of 4- acetoxybicyclo [2.2. 2] octan-2-ones and 4-chlorobicyclo [2.2. 2] octan-2-ones. An acid- ...