Synthetic applications of cyclic. alpha.-chloro ethers and thioethers. 4. Use of (thio) acetal esters as reagents for the protection of alcohols. Synthesis of 2- …

CG Kruse, EK Poels, FL Jonkers…

Index: Kruse,C.G. et al. Journal of Organic Chemistry, 1978 , vol. 43, p. 3548 - 3553

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Citation Number: 40

Abstract

Polymerization was effectively retarded by addition of triethylamine. In more polar solvents, mixtures of 2-C1-THT and 2, 3-diCl-THT were formed and the yield of chlorinated products decreased (see Table I). The reaction exhibits the same, characteristics as the reaction with chlorine which was studied by Wilson and Albert. 7 It is generally acceptedlo that upon reaction of sulfides with chlorinating agents, sulfonium salts are formed in the first step. In ...