Chemistry Letters

The Catalytic Friedel-Crafts Acylation Reaction Using a Catalyst Generated from GaCl3 and a Silver Salt.

T Mukaiyama, T Ohno, T Nishimura, S Suda…

Index: Mukaiyama, Teruaki; Ohno, Takashi; Nishimura, Takashi; Suda, Shinji; Kobayashi, Shu Chemistry Letters, 1991 , # 6 p. 1059 - 1062

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Citation Number: 59

Abstract

In the presence of a catalyst generated from GaCl 3 and a silver salt (AgClO 4 or AgSbF 6), the Friedel-Crafts acylation reaction of aromatic compounds such as anisole and veratrole with acid anhydrides smoothly proceeds to afford the corresponding aromatic ketones in high yields.