Tetrahedron letters

Oxovanadium-induced oxidative desilylation for the selective synthesis of 1, 4-diketones

T Fujii, T Hirao, Y Ohshiro

Index: Fujii Takashi; Hirao, Toshikazu; Ohshiro, Yoshiki Tetrahedron Letters, 1992 , vol. 33, # 39 p. 5823 - 5826

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Citation Number: 56

Abstract

Download full text in PDF Opens in a new window. Article suggestions will be shown in a dialog on return to ScienceDirect. ... Please enable JavaScript to use all the features on this page. ... Silyl enol ethers underwent the VO(OR)Cl 2 -induced homo- or cross-coupling giving 1,4-diketones selectively via one-electron oxidative desilylation. ... Oxidation of silyl enol ethers with VO(OR)Cl 2 gave unsymmetrical 1,4-diketones selectively. ... A general experimental ...