Preparation and characterization of tetraaza [14] annulene and its nickel (ii) and copper (II) complexes with crown ether functionalities

…, M Shimoda, M Hashimoto

Index: Sakata, Kazunori; Shimoda, Manabu; Hashimoto, Mamoru Journal of Heterocyclic Chemistry, 1996 , vol. 33, # 6 p. 1593 - 1598

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Citation Number: 15

Abstract

Abstract Three new organic hosts are described that contain a tetraaza [14] annulene core to which two crown ether voids are attached. These hosts include a free base tetraaza [14] annulene and/or its complexes with benzo-15-crown-5 rings. The crown tetraaza [14] annulene is synthesized from tetraaza [14] annulene and 4′-chloroformylbenzo-15-crown- 5. Its nickel (II) and copper (II) complexes are prepared in a similar manner as above. In ...