Synthetic reactions of dimethylformamide. XIII. β-Bromoacraldehydes

Z Arnold, A Holý

Index: Arnold,Z.; Holy,A. Collection of Czechoslovak Chemical Communications, 1961 , vol. 26, p. 3059 - 3073

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Citation Number: 79

Abstract

The previous papers of this series contained descriptions of several general methods of preparation of~-chloroacraldehydes (I a) 1-3. One of these methods, the fortnyI-ation of ketones with dimethylformamide-phosphorus oxychloride and with dimethylformamide- carbonyl chloride, has been used later by other authors4, 5. The present paper describes the preparation of~-bromoacraldehydes (Ib) which have not been known so far with but a ...