Journal of the American Chemical Society

ORIENTATION IN THE BENZENE RING. THE CHLORINATION OF PYROGALLOL-2, 6-DIMETHYL ETHER

AA Levine

Index: Levine Journal of the American Chemical Society, 1926 , vol. 48, p. 2720

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Citation Number: 1

Abstract

Oxidation of 3-Chloropyrogallol-2, 6-dimethyl Ether.--Three g. of the phenol dcscribed above was dissolved in 50 cc. of 207, acetic acid. To this solution was added 2.5 g. of chromium trioxide. 3, 3'-Dichloro-2, 6, 2', 6'-tetramethoxy-biphenoquinone precipitated on standing; yield, 6070. The filtrate, on extraction with ether, gave a small quantity of presumably 3- chloro-2, 6-dimethoxy-p-benzoquinone, since on bromination 3-chloro-2, 6-dimethoxy-~- ...