Tetranuclear Polypyridyl Complexes of RuII and FeII: Synthesis, Electrochemical, Photophysical and Photochemical Behaviour

…, D Daveloose, A Deronzier, JC Leprêtre

Index: Lombard, Jean; Romain, Sophie; Dumas, Stephane; Chauvin, Jerome; Collomb, Marie-Noelle; Daveloose, Denis; Deronzier, Alain; Lepretre, Jean-Claude European Journal of Inorganic Chemistry, 2005 , # 16 p. 3320 - 3330

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Citation Number: 11

Abstract

Abstract Three heterotetranuclear complexes [{Ru II (bpy) 2 (LL n)} 3 Fe II] 8+{bpy= 2, 2'- bipyridine, n= 2, 4, 6; denoted [{Ru (LL n)} 3 Fe] 8+}, in which one iron centre is complexed by three Ru II-tris-bipyridine-like moieties containing covalently bridging bis-bipyridine LL n ligands, have been synthesised and characterised. The stability and the electrochemical, photophysical and photochemical properties of these complexes have been investigated ...