The Journal of Organic Chemistry

Comparison of the reactivity of CF3OX (X= Cl, F) with some simple alkenes

KK Johri, DD DesMarteau

Index: Journal of Organic Chemistry, , vol. 48, # 2 p. 242 - 250

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Citation Number: 64

Abstract

... Chem., Vol. ... field, JAB = 9.5, JBc = 16.0, 3&7B = 9.0, JAc = 0.8 Hz; (CF3%H2FB) 4A* -78.7 (m), 4 ~ * very high field, J m = 15.5, 3 J ~ = 8.2 Hz. ... The chemistry of CF,OCl has received much less at- tention, but a variety of reactions clearly show the positive halogen character of the ...