A new ruthenium complex,[Ru (bpy) 2dppz-idzo] 2+(bpy= 2, 2′-bipyridine, dppz-idzo= dipyrido-[3, 2-a: 2′, 3′-c] phenazine-imidazolone), was synthesized and characterized. The luminescent titrations showed that the Ru-complex exhibited an outstanding “light switch” effect with an emission enhancement factor of about 300 in the presence of G- quadruplex DNA in a K+ solution. This remarkable “light switch” behavior can even be ...