Organic letters

Diels–Alder Construction of Regiodifferentiated meta-Amino Phenols and Derivatives

MG Weaver, WJ Bai, SK Jackson, TRR Pettus

Index: Bai, Wen-Ju; Jackson, Stephen K.; Pettus, Thomas R. R. Organic Letters, 2012 , vol. 14, # 15 p. 3862 - 3865

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Citation Number: 8

Abstract

Synthetic access to regiodifferentiated meta-amino phenols is described. The strategy relies upon distinct deprotonation conditions to afford regioisomeric thermodynamic and kinetic dienes that undergo a tandem Diels–Alder and retro-Diels–Alder sequence with assorted