Tetrahedron letters

N-(Diphenylphosphinothioyl) hydroxylamine Transposition of O and S in its O-benzoyl derivative

MJP Harger

Index: Harger, Martin J. P. Tetrahedron Letters, 1993 , vol. 34, # 49 p. 7947 - 7948

Full Text: HTML

Citation Number: 2

Abstract

Abstract N-(Diphenylphosphinothioyl) hydroxylamine has been prepared from Ph 2 P (S) Cl using H 2 NOSiMe 3. The derivative Ph 2 P (S) NHOCOPh rearranges to Ph 2 P (O) NHSCOPh with base; this transposition of O and S seems to require a 3-membered ring

~0%

The titanium tetrachloride induced synthesis of N-phosphinoy...

[Jennings, W. Brian; Lovely, Carl J. Tetrahedron, 1991 , vol. 47, # 29 p. 5561 - 5568]

Computational study of the Curtius-like rearrangements of ph...

[Freeman, Sally; Harger, Martin J. P. Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1989 , p. 571 - 578]

The origin of the amide formed in the photochemical reaction...

[Freeman, Sally; Harger, Martin J. P. Journal of the Chemical Society, Chemical Communications, 1985 , # 5 p. 241 - 242]

The titanium tetrachloride induced synthesis of N-phosphinoy...

[Tetrahedron, , vol. 47, # 29 p. 5561 - 5568]

N-(Diphenylphosphinothioyl) hydroxylamine Transposition of O...

[Tetrahedron Letters, , vol. 34, # 49 p. 7947 - 7948]