… copolymer synthesized by ring??opening metathesis copolymerization of cyclooctene and macrocyclic olefin and its hydrolysis to give carboxyl??telechelic polymer

…, W Wang, L Ding, J Liu, D Yang, L Wei…

Index: Xie, Meiran; Wang, Weizhen; Ding, Liang; Liu, Jingwei; Yang, Dan; Wei, Ling; Zhang, Yiqun Journal of Polymer Science, Part A: Polymer Chemistry, 2010 , vol. 48, # 2 p. 380 - 388

Full Text: HTML

Citation Number: 9

Abstract

Abstract A novel cleavable multiblock copolymer was synthesized by ring-opening metathesis polymerization (ROMP) of cyclooctene (COE) and a flexible 27-membered macrocyclic olefin (MCO), which is acted as the spacer to collect the polymer structure block by block. MCO 2 was prepared via ring-closing metathesis of the long chain alkyldiene, and then 2 was well-conducted ROMP with COE to provide the multiblock copolymer [Poly ( ...