The Journal of organic chemistry

De novo synthesis of stable tetrahydroporphyrinic macrocycles: Bacteriochlorins and a tetradehydrocorrin

HJ Kim, JS Lindsey

Index: Sakai; Suzuki; Nunami; Yoneda; Onoda; Iwasawa Chemical and pharmaceutical bulletin, 1980 , vol. 28, # 8 p. 2384 - 2393

Full Text: HTML

Citation Number: 118

Abstract

... Volume: Page ... variety of photochemical studies, and corroles or octadehydrocorrins are used as model corrins in organometallic chemistry and studies ... 2-formyl-4-(4-methylphenyl)pyrrole (δ 7.20−7.22 and 7.36−7.38 ppm), also showed similar chemical shifts for ...

 Related Synthetic Route
3-pyridin-4-yl-pyrrole-2,4-dicarboxylic acid dimethyl ester Structure

76304-45-5

3-pyridin-4-yl-...

~64%

3-thiophen-2-yl-1H-pyrrole Structure

52707-48-9

3-thiophen-2-yl...

dimethyl 3-thiophen-2-yl-1H-pyrrole-2,4-dicarboxylate Structure

61726-73-6

dimethyl 3-thio...

~%

3-thiophen-2-yl-1H-pyrrole Structure

52707-48-9

3-thiophen-2-yl...

N/A Structure

76203-01-5

N/A

~%

3-thiophen-2-yl-1H-pyrrole Structure

52707-48-9

3-thiophen-2-yl...

3-benzo[1,3]dioxol-5-yl-pyrrole-2,4-dicarboxylic acid dimethyl ester Structure

61726-71-4

3-benzo[1,3]dio...

~90%

3-(1,3-benzodioxol-5-yl)-1H-pyrrole-2,4-dicarboxylic acid Structure

63761-12-6

3-(1,3-benzodio...

Structure

68001-87-6

~%

3-(1,3-benzodioxol-5-yl)-1H-pyrrole-2,4-dicarboxylic acid Structure

63761-12-6

3-(1,3-benzodio...

3-(4-methoxyphenyl)-1H-pyrrole-2,4-dicarboxylic acid Structure

76304-42-2

3-(4-methoxyphe...

~83%

3-(4-methoxyphenyl)-1H-pyrrole Structure

63761-14-8

3-(4-methoxyphe...

N/A Structure

52921-24-1

N/A

~%

3-(4-methoxyphenyl)-1H-pyrrole Structure

63761-14-8

3-(4-methoxyphe...

dimethyl 3-(4-methylphenyl)-1H-pyrrole-2,4-dicarboxylate Structure

61726-70-3

dimethyl 3-(4-m...

~59%

3-(4-methylphenyl)-1H-pyrrole Structure

76304-54-6

3-(4-methylphen...

methyl (Z)-2-isocyano-3-(p-tolyl)acrylate Structure

68001-89-8

methyl (Z)-2-is...

~%

3-(4-methylphenyl)-1H-pyrrole Structure

76304-54-6

3-(4-methylphen...

3-phenyl-1H-pyrrole-2,4-dicarboxylic acid Structure

76304-38-6

3-phenyl-1H-pyr...

~58%

3-Phenyl-1H-pyrrole Structure

27649-43-0

3-Phenyl-1H-pyrrole

dimethyl 3-phenyl-1H-pyrrole-2,4-dicarboxylate Structure

52921-23-0

dimethyl 3-phen...

~%

3-Phenyl-1H-pyrrole Structure

27649-43-0

3-Phenyl-1H-pyrrole

methyl 2-isocyano-3-phenylprop-2-enoate Structure

76202-88-5

methyl 2-isocya...

~%

3-Phenyl-1H-pyrrole Structure

27649-43-0

3-Phenyl-1H-pyrrole

3-(pyridin-3-yl)-1H-pyrrole-2,4-dicarboxylic acid Structure

76304-43-3

3-(pyridin-3-yl...

~72%

3-(1H-pyrrol-3-yl)pyridine Structure

76304-55-7

3-(1H-pyrrol-3-...

dimethyl 3-pyridin-3-yl-1H-pyrrole-2,4-dicarboxylate Structure

52921-26-3

dimethyl 3-pyri...

~%

3-(1H-pyrrol-3-yl)pyridine Structure

76304-55-7

3-(1H-pyrrol-3-...

3-(pyridin-4-yl)-1H-pyrrole-2,4-dicarboxylic acid Structure

76304-44-4

3-(pyridin-4-yl...

~73%

4-(1H-pyrrol-3-yl)pyridine Structure

76304-56-8

4-(1H-pyrrol-3-...

p-Formylpyridine Structure

872-85-5

p-Formylpyridine

~%

4-(1H-pyrrol-3-yl)pyridine Structure

76304-56-8

4-(1H-pyrrol-3-...

dimethyl 3-(pyridin-4-yl)-1H-pyrrole-2,4-dicarboxylate Structure

76304-61-5

dimethyl 3-(pyr...

~%

4-(1H-pyrrol-3-yl)pyridine Structure

76304-56-8

4-(1H-pyrrol-3-...

dimethyl 3-(2-bromophenyl)-1H-pyrrole-2,4-dicarboxylate Structure

76304-29-5

dimethyl 3-(2-b...

~%

3-(2-Bromo-phenyl)-1H-pyrrole Structure

76304-46-6

3-(2-Bromo-phen...

methyl 3-(2-bromophenyl)-2-isocyanoprop-2-enoate Structure

76202-94-3

methyl 3-(2-bro...

~%

3-(2-Bromo-phenyl)-1H-pyrrole Structure

76304-46-6

3-(2-Bromo-phen...

Methyl isocyanoacetate Structure

39687-95-1

Methyl isocyano...

methyl 2-isocyano-3-phenylprop-2-enoate Structure

76202-88-5

methyl 2-isocya...

~70%

dimethyl 3-phenyl-1H-pyrrole-2,4-dicarboxylate Structure

52921-23-0

dimethyl 3-phen...

methyl (Z)-2-isocyano-3-(p-tolyl)acrylate Structure

68001-89-8

methyl (Z)-2-is...

Methyl isocyanoacetate Structure

39687-95-1

Methyl isocyano...

~70%

dimethyl 3-(4-methylphenyl)-1H-pyrrole-2,4-dicarboxylate Structure

61726-70-3

dimethyl 3-(4-m...

N/A Structure

76304-39-7

N/A

~63%

3-(2-CHLORO-PHENYL)-1H-PYRROLE Structure

71845-14-2

3-(2-CHLORO-PHE...

dimethyl 3-(2-chlorophenyl)-1H-pyrrole-2,4-dicarboxylate Structure

76304-26-2

dimethyl 3-(2-c...

~%

3-(2-CHLORO-PHENYL)-1H-PYRROLE Structure

71845-14-2

3-(2-CHLORO-PHE...

methyl 3-(2-chlorophenyl)-2-isocyanoprop-2-enoate Structure

76202-92-1

methyl 3-(2-chl...

~%

3-(2-CHLORO-PHENYL)-1H-PYRROLE Structure

71845-14-2

3-(2-CHLORO-PHE...

N/A Structure

76203-01-5

N/A

Methyl isocyanoacetate Structure

39687-95-1

Methyl isocyano...

~69%

dimethyl 3-thiophen-2-yl-1H-pyrrole-2,4-dicarboxylate Structure

61726-73-6

dimethyl 3-thio...


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